Aromatic rings with rotated adjacent chromophores
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Abstract/Description: | A compound having nonlinear optical properties of the general formula: Ar1 CR1 ?CR2 (Ar2 CR3 ?CR4)n Ar3 (I)wherein, n represents a whole number; R1, R1, R3 and R4 groups are independently selected from H, branched aliphatic, straight chain aliphatic, branched silane or straight chain silane; Ar1 and Ar3 are aromatic radicals having a substituent in at least one position adjacent to a site of attachment of the C?C double bond and having at least one electron withdrawing or electron donating substituent in at least one of the remaining positions; Ar2 is an aromatic radical having a substituent in at least one position adjacent to a site of attachment of the C?C double bond; with the proviso that the substituent in at least one position adjacent to the site of attachment of the C?C double bond and R1, R2, R3 and R4 groups are sufficiently large to cause Ar1, Ar2 and Ar3 to rotate approximately perpendicular to a plane containing each adjacent C?C double bond and its substituents and a nonlinear optical device including a compound of the general formula (I). |
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Subject(s): | 359/321 252/589 359/245 359/251 359/256 359/320 359/322 359/323 430/71 G9B/7.171 G9B/7.181 G9B/7.186 |
Date Issued: | 1998-03-24 |
Title: | Aromatic rings with rotated adjacent chromophores. |
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Name(s): |
The University of Toledo, assignee Gano, James E., inventor Sekher, Padmanabhan, inventor |
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Type of Resource: | text | |
Genre: | patent | |
Publisher: | United States Patent and Trademark Office | |
Other Date: | Date Filed: 1996-09-10 | |
Date Issued: | 1998-03-24 | |
Physical Form: | application/pdf | |
Extent: | 7 p. | |
Abstract/Description: | A compound having nonlinear optical properties of the general formula: Ar1 CR1 ?CR2 (Ar2 CR3 ?CR4)n Ar3 (I)wherein, n represents a whole number; R1, R1, R3 and R4 groups are independently selected from H, branched aliphatic, straight chain aliphatic, branched silane or straight chain silane; Ar1 and Ar3 are aromatic radicals having a substituent in at least one position adjacent to a site of attachment of the C?C double bond and having at least one electron withdrawing or electron donating substituent in at least one of the remaining positions; Ar2 is an aromatic radical having a substituent in at least one position adjacent to a site of attachment of the C?C double bond; with the proviso that the substituent in at least one position adjacent to the site of attachment of the C?C double bond and R1, R2, R3 and R4 groups are sufficiently large to cause Ar1, Ar2 and Ar3 to rotate approximately perpendicular to a plane containing each adjacent C?C double bond and its substituents and a nonlinear optical device including a compound of the general formula (I). | |
Identifier(s): |
utpatents-US5731890 (IID) Patent No.: US5731890 (patno) Appl. No.: 08/711503 (appno) |
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Subject(s): |
359/321 252/589 359/245 359/251 359/256 359/320 359/322 359/323 430/71 G9B/7.171 G9B/7.181 G9B/7.186 |
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Held by: | United States Patent and Trademark Office (USPTO) Public Search Facility | |
Location: | University of Toledo Digital Repository | |
Rights Statement: | No Copyright - United States | |
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